Электролюминесценция: Оптические и электрические свойства и применение

Optical and electrical phenomenon

Electroluminescence (EL) is an optical and electrical phenomenon, in which a material emits light in response to the passage of an electric current or to a strong electric field. This is distinct from black body light emission resulting from heat (incandescence), chemical reactions (chemiluminescence), reactions in a liquid (electrochemiluminescence), sound (sonoluminescence), or other mechanical action (mechanoluminescence), or
organic electroluminescence.

Electroluminescence is the result of radiative recombination of electrons & holes in a material, usually a semiconductor. The excited electrons release their energy as photons light. Prior to recombination, electrons and holes may be separated either by doping the material to form a p n junction (in semiconductor electroluminescent devices such as light emitting diodes) or through excitation by impact of high energy electrons accelerated by a strong electric field (as with the phosphors in electroluminescent displays). It has been recently shown that as a solar cell improves its light to electricity efficiency (improved open circuit voltage), it will also improve its electricity to light (EL) efficiency.

Electroluminescent technologies have low power consumption compared to competing lighting technologies, such as neon or fluorescent lamps. This, together with the thinness of the material, has made EL technology valuable to the advertising industry. Relevant advertising applications include electroluminescent billboards and signs. EL manufacturers can control precisely which areas of an electroluminescent sheet illuminate, and when. This has given advertisers the ability to create more dynamic advertising that is still compatible with traditional advertising spaces. An EL film is a so called Lambertian radiator: unlike with neon lamps, filament lamps, or LEDs, the brightness of the surface appears the same from all angles of view; electroluminescent light is not directional. The light emitted from the surface is perfectly homogeneous and is well perceived by the eye. EL film produces single frequency (monochromatic) light that has a very narrow bandwidth, is uniform and visible from a great distance. In principle, EL lamps can be made in any color. However, the commonly used greenish color closely matches the peak sensitivity of human vision, producing the greatest apparent light output for the least electrical power input. Unlike neon and fluorescent lamps, EL lamps are not negative resistance devices so no extra circuitry is needed to regulate the amount of current flowing through them. A new technology now being used is based on multispectral phosphors that emit light from 600 to 400nm depending on the drive frequency; this is similar to the color changing effect seen with aqua EL sheet but on a larger scale.

The most common electroluminescent (EL) devices are composed of either powder (primarily used in lighting applications) or thin films (for information displays.)

Light emitting capacitor, or LEC, is a term used since at least 1961 to describe electroluminescent panels. General Electric has patents dating to 1938 on flat electroluminescent panels that are still made as night lights and backlights for instrument panel displays. Electroluminescent panels are a capacitor where the dielectric between the outside plates is a phosphor that gives off photons when the capacitor is charged. By making one of the contacts transparent, the large area exposed emits light. Electroluminescent automotive instrument panel backlighting, with each gauge pointer also an individual light source, entered production on 1960 Chrysler and Imperial passenger cars, and was continued successfully on several Chrysler vehicles through 1967 and marketed as "Panelescent Lighting".

The Sylvania Lighting Division in Salem and Danvers, Massachusetts, produced and marketed an EL night light, under the trade name Panelescent at roughly the same time that the Chrysler instrument panels entered production. These lamps have proven extremely reliable, with some samples known to be still functional after nearly 50 years of continuous operation. Later in the 1960s, Sylvania's Electronic Systems Division in Needham, Massachusetts developed and manufactured several instruments for the Apollo Lunar Module and Command Module using electroluminescent display panels manufactured by the Electronic Tube Division of Sylvania at Emporium, Pennsylvania. Raytheon in Sudbury, Massachusetts manufactured the Apollo Guidance Computer, which used a Sylvania electroluminescent display panel as part of its display keyboard interface (DSKY).

Powder phosphor based electroluminescent panels are frequently used as backlights for liquid crystal displays. They readily provide gentle, even illumination for the entire display while consuming relatively little electric power. This makes them convenient for battery operated devices such as pagers, wristwatches, and computer controlled thermostats, and their gentle green cyan glow is common in the technological world. EL backlights require relatively high voltage (between 60 and 600 volts). For battery operated devices, this voltage must be generated by a boost converter circuit within the device. This converter often makes a faintly audible whine or siren sound while the backlight is activated. Line voltage operated devices may be activated directly from the power line; some electroluminescent nightlights operate in this fashion. Brightness per unit area increases with increased voltage and frequency.

Thick film dielectric electroluminescent technology (TDEL) is a phosphor based flat panel display technology developed by Canadian company iFire Technology Corp. TDEL is based on inorganic electroluminescent (IEL) technology that combines both thick and thin film processes. The TDEL structure is made with glass or other substrates, consisting of a thick film dielectric layer and a thin film phosphor layer sandwiched between two sets of electrodes to create a matrix of pixels. Inorganic phosphors within this matrix emit light in the presence of an alternating electric field.

Color By Blue (CBB) was developed in 2003. The Color By Blue process achieves higher luminance and better performance than the previous triple pattern process, with increased contrast, grayscale rendition, and color uniformity across the panel. Color By Blue is based on the physics of photoluminescence. High luminance inorganic blue phosphor is used in combination with specialized color conversion materials, which absorb the blue light and re emit red or green light, to generate the other colors.

Electroluminescent lighting is now used as an application for public safety identification involving alphanumeric characters on the roof of vehicles for clear visibility from an aerial perspective. Electroluminescent lighting, especially electroluminescent wire (EL wire), has also made its way into clothing as many designers have brought this technology to the entertainment and nightlife industry. From 2006, t shirts with an electroluminescent panel stylized as an audio equalizer, the T Qualizer, saw a brief period of popularity. Engineers have developed an electroluminescent "skin" that can stretch more than six times its original size while still emitting light. This hyper elastic light emitting capacitor (HLEC) can endure more than twice the strain of previously tested stretchable displays. It consists of layers of transparent hydrogel electrodes sandwiching an insulating elastomer sheet. The elastomer changes luminance and capacitance when stretched, rolled, and otherwise deformed. In addition to its ability to emit light under a strain of greater than 480% of its original size, the group's HLEC was shown to be capable of being integrated into a soft robotic system. Three six layer HLEC panels were bound together to form a crawling soft robot, with the top four layers making up the light up skin and the bottom two the pneumatic actuators. The discovery could lead to significant advances in health care, transportation, electronic communication and other areas.