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Kingston is a city in and the county seat of Roane County, Tennessee, United States. This city is thirty six miles southwest of Knoxville. It had a population of 5,934 at the 2010 United States census, and is included in the Harriman, Tennessee Micropolitan Statistical Area. Kingston is adjacent to Watts Bar Lake.

Kingston has its roots in Fort Southwest Point, which was built just south of present day Kingston in 1792. At the time, Southwest Point was on the fringe of the legal settlement area for Euro Americans. A Cherokee village, headed by Chief Tollunteeskee, was situated just across the river, at what is now Rockwood. In 1805, Colonel Return J. Meigs, who operated out of Southwest Point, was appointed Cherokee Agent, effectively moving the agency from the Tellico Blockhouse to Southwest Point. The city of Kingston was established on October 23, 1799, as part of an effort to partition Knox County (the initial effort to form a separate county failed, but succeeded two years later). Kingston was named after Major Robert King, an officer at Fort Southwest Point in the 1790s. On September 21, 1807, Kingston was Tennessee's state capital for one day. The Tennessee General Assembly convened in Kingston that day due to an agreement with the Cherokee, who had been told that if the Cherokee Nation ceded the land that is now Roane County, Kingston would become the capital of Tennessee. After adjourning that day, the Assembly resumed meeting in Knoxville. At the outset of the Civil War in 1861, Kingston was selected as the site of the third session of the East Tennessee Convention, which attempted to form a new, Union aligned state in East Tennessee. Due to the Confederate occupation of the region, however, this third session, which was scheduled for August 1861, never took place. In October 1861, William B. Carter and several co conspirators planned the East Tennessee bridge burnings from a command post in Kingston. On November 24, 1863, Confederate Cavalry under Joseph Wheeler numbering about 500–1,000 men tried to take Kingston from the Union in the Battle of Kingston, but they were unsuccessful. In 1955, the Tennessee Valley Authority completed work on the Kingston Fossil Plant, which at the time was the world's largest coal burning power plant. The plant, which consumes roughly of coal daily, can produce up to 1,456 megawatts of electricity. The plant's 1,000 foot (305 m) smokestacks are a familiar sight to those driving on the Roane County stretch of Interstate 40. On December 22, 2008, a impoundment containing fly ash slurry from the power plant broke, spilling more than of waste into the surrounding area.

+Kingston racial composition Race Number Percentage White (non Hispanic) 5,309 89.18% Black or African American (non Hispanic) 203 3.41% Native American 9 0.15% Asian 56 0.94% Pacific Islander 2 0.03% Other/Mixed 242 4.07% Hispanic or Latino 132 2.22%
As of the 2020 United States census, there were 5,953 people, 2,225 households, and 1,335 families residing in the city.

As of the census of 2000, there were 5,264 people, 2,263 households, and 1,532 families residing in the city. The population density was There were 2,478 housing units at an average density of The racial makeup of the city was 93.75% White, 3.55% African American, 0.23% Native American, 0.49% Asian, 0.06% Pacific Islander, 0.23% from other races, and 1.69% from two or more races. Hispanic or Latino of any race were 0.97% of the population. There were 2,263 households, out of which 26.0% had children under the age of 18 living with them, 54.3% were married couples living together, 10.8% had a female householder with no husband present, and 32.3% were non families. 29.6% of all households were made up of individuals, and 14.8% had someone living alone who was 65 years of age or older. The average household size was 2.25 and the average family size was 2.77. In the city, the population was spread out, with 20.5% under the age of 18, 8.2% from 18 to 24, 26.0% from 25 to 44, 24.8% from 45 to 64, and 20.4% who were 65 years of age or older. The median age was 42 years. For every 100 females there were 88.8 males. For every 100 females age 18 and over, there were 87.0 males. The median income for a household in the city was $34,071, and the median income for a family was $44,979. Males had a median income of $40,186 versus $22,971 for females. The per capita income for the city was $20,301. About 6.0% of families and 10.0% of the population were below the poverty line, including 16.6% of those under age 18 and 8.9% of those age 65 or over.