Нанометрлік тесікті мөлдір материалдар

Filter material with homogeneously sized pores in the nanometer range

A molecular sieve is a material with pores of uniform size. These pore diameters are similar in size to small molecules, and thus large molecules cannot enter or be adsorbed, while smaller molecules can. As a mixture of molecules migrates through the stationary bed of porous, semi solid substance referred to as a sieve (or matrix), the components of the highest molecular weight (which are unable to pass into the molecular pores) leave the bed first, followed by successively smaller molecules. Some molecular sieves are used in size exclusion chromatography, a separation technique that sorts molecules based on their size. Another important use is as a desiccant. Most of molecular sieves are aluminosilicate zeolites with Si/Al molar ratio less than 2, but there are also examples of activated charcoal and silica gel. The pore diameter of a molecular sieve is measured in ångströms (Å) or nanometres (nm). According to IUPAC notation, microporous materials have pore diameters of less than 2 nm (20 Å) and macroporous materials have pore diameters of greater than 50 nm (500 Å); the mesoporous category thus lies in the middle with pore diameters between 2 and 50 nm (20–500 Å).

Molecular sieves can be microporous, mesoporous, or macroporous material.

Silicon dioxide (used to make silica gel): 24 Å (2.4 nm)

Molecular sieves are often utilized in the petroleum industry, especially for drying gas streams. For example, in the liquid natural gas (LNG) industry, the water content of the gas needs to be reduced to less than 1 ppmv to prevent blockages caused by ice or methane clathrate. In the laboratory, molecular sieves are used to dry solvent. "Sieves" have proven to be superior to traditional drying techniques, which often employ aggressive desiccants. Under the term zeolites, molecular sieves are used for a wide range of catalytic applications. They catalyze isomerisation, alkylation, and epoxidation, and are used in large scale industrial processes, including hydrocracking and fluid catalytic cracking. They are also used in the filtration of air supplies for breathing apparatus, for example those used by scuba divers and firefighters. In such applications, air is supplied by an air compressor and is passed through a cartridge filter which, depending on the application, is filled with molecular sieve and/or activated carbon, finally being used to charge breathing air tanks. Such filtration can remove particulates and compressor exhaust products from the breathing air supply.

The U. S. FDA has as of April 1, 2012, approved sodium aluminosilicate for direct contact with consumable items under 21 CFR 182.2727. Prior to this approval the European Union had used molecular sieves with pharmaceuticals and independent testing suggested that molecular sieves meet all government requirements but the industry had been unwilling to fund the expensive testing required for government approval.

Methods for regeneration of molecular sieves include pressure change (as in oxygen concentrators), heating and purging with a carrier gas (as when used in ethanol dehydration), or heating under high vacuum. Regeneration temperatures range from to depending on molecular sieve type. In contrast, silica gel can be regenerated by heating it in a regular oven to for two hours. However, some types of silica gel will "pop" when exposed to enough water. This is caused by breakage of the silica spheres when contacting the water.

Production of 4A sieve is relatively straightforward as it requires neither high pressures nor particularly high temperatures. Typically aqueous solutions of sodium silicate and sodium aluminate are combined at 80 °C. The solvent impregnated product is "activated" by "baking" at 400 °C 4A sieves serve as the precursor to 3A and 5A sieves through cation exchange of sodium for potassium (for 3A) or calcium (for 5A)

4A molecular sieves are widely used to dry laboratory solvents. They can absorb water and other molecules with a critical diameter less than 4 Å such as NH3, H2S, SO2, CO2, C2H5OH, C2H6, and C2H4. They are widely used in the drying, refining and purification of liquids and gases (such as the preparation of argon).

These molecular sieves are used to assist detergents as they can produce demineralized water through calcium ion exchange, remove and prevent the deposition of dirt. They are widely used to replace phosphorus. The 4A molecular sieve plays a major role to replace sodium tripolyphosphate as detergent auxiliary in order to mitigate the environmental impact of the detergent. It also can be used as a soap forming agent and in toothpaste.

4A molecular sieves can purify sewage of cationic species such as ammonium ions, Pb2+, Cu2+, Zn2+ and Cd2+. Due to the high selectivity for NH4+ they have been successfully applied in the field to combat eutrophication and other effects in waterways due to excessive ammonium ions. 4A molecular sieves have also been used to remove heavy metal ions present in water due to industrial activities.

Five ångström (5A) molecular sieves are often utilized in the petroleum industry, especially for the purification of gas streams and in the chemistry laboratory for separating compounds and drying reaction starting materials. They contain tiny pores of a precise and uniform size, and are mainly used as an adsorbent for gases and liquids. Five ångström molecular sieves are used to dry natural gas, along with performing desulfurization and decarbonation of the gas. They can also be used to separate mixtures of oxygen, nitrogen and hydrogen, and oil wax n hydrocarbons from branched and polycyclic hydrocarbons. Five ångström molecular sieves are stored at room temperature, with a relative humidity less than 90% in cardboard barrels or carton packaging. The molecular sieves should not be directly exposed to the air and water, acids and alkalis should be avoided.

Molecular sieves are available in diverse shape and sizes. But the spherical beads have advantage over other shapes as they offer lower pressure drop, are attrition resistant as they do not have any sharp edges, and have good strength, i. e. crush force required per unit area is higher. Certain beaded molecular sieves offer lower heat capacity thus lower energy requirements during regeneration. The other advantage of using beaded molecular sieves is bulk density is usually higher than other shape, thus for same adsorption requirement molecular sieve volume required is less. Thus while doing de bottlenecking, one may use beaded molecular sieves, load more adsorbent in same volume, and avoid any vessel modifications.