Силикат натрия: состав, свойства и история получения жидкого стекла

Hygroscopic chemical compound of variable Na2O/SiO2 ratio precursor of waterglass

Sodium silicate is a generic name for chemical compounds with the formula or ·, such as sodium metasilicate , sodium orthosilicate , and sodium pyrosilicate The anions are often polymeric. These compounds are generally colorless transparent solids or white powders, and soluble in water in various amounts. Sodium silicate is also the technical and common name for a mixture of such compounds, chiefly the metasilicate, also called waterglass, water glass, or liquid glass. The product has a wide variety of uses, including the formulation of cements, coatings, passive fire protection, textile and lumber processing, manufacture of refractory ceramics, as adhesives, and in the production of silica gel. The commercial product, available in water solution or in solid form, is often greenish or blue owing to the presence of iron containing impurities. In industry, the various grades of sodium silicate are characterized by their SiO2:Na2O weight ratio (which can be converted to molar ratio by multiplication with 1.032). The ratio can vary between 1:2 and 3.75:1. Grades with ratio below 2.85:1 are termed alkaline. Those with a higher SiO2:Na2O ratio are described as neutral.

Soluble silicates of alkali metals (sodium or potassium) were observed by European alchemists already in the 1500s. Giambattista della Porta observed in 1567 that tartari salis (cream of tartar, potassium hydrogen tartrate) caused powdered crystallum (quartz) to melt at a lower temperature. Other possible early references to alkali silicates were made by Basil Valentine in 1520, and by Agricola in 1550. Around 1640, Jean Baptist van Helmont reported the formation of alkali silicates as a soluble substance made by melting sand with excess alkali, and observed that the silica could be precipitated quantitatively by adding acid to the solution. In 1646, Glauber made potassium silicate, which he called liquor silicum, by melting potassium carbonate (obtained by calcinating cream of tartar) and sand in a crucible, and keeping it molten until it ceased to bubble (due to the release of carbon dioxide). The mixture was allowed to cool and then was ground to a fine powder. When the powder was exposed to moist air, it gradually formed a viscous liquid, which Glauber called "Oleum oder Liquor Silicum, Arenæ, vel Crystallorum" (i. e., oil or solution of silica, sand or quartz crystal). However, it was later claimed that the substances prepared by those alchemists were not waterglass as it is understood today. That would have been prepared in 1818 by Johann Nepomuk von Fuchs, by treating silicic acid with an alkali; the result being soluble in water, "but not affected by atmospheric changes". The terms "water glass" and "soluble glass" were used by Leopold Wolff in 1846, by Émile Kopp in 1857, and by Hermann Krätzer in 1887. In 1892, Rudolf Von Wagner distinguished soda, potash, double (soda and potash), and fixing (i. e., stabilizing) as types of water glass. The fixing type was "a mixture of silica well saturated with potash water glass and a sodium silicate" used to stabilize inorganic water color pigments on cement work for outdoor signs and murals.

Sodium silicates are colorless glassy or crystalline solids, or white powders. Except for the most silicon rich ones, they are readily soluble in water, producing alkaline solutions. When dried up it still can be rehydrated back in water. Sodium silicates are stable in neutral and alkaline solutions. In acidic solutions, the silicate ions react with hydrogen ions to form silicic acids, which tend to decompose into hydrated silicon dioxide gel. Heated to drive off the water, the result is a hard translucent substance called silica gel, widely used as a desiccant. It can withstand temperatures up to 1100 °C.

Though unprofitable, Na2SiO3 is a byproduct of Bayer process which is often converted to calcium silicate (Ca2SiO4).

It is used in detergent auxiliaries such as complex sodium disilicate and modified sodium disilicate. The detergent granules gain their ruggedness from a coating of silicates.

Sodium silicate is used, along with magnesium silicate, in muffler repair and fitting paste. When dissolved in water, both sodium silicate and magnesium silicate form a thick paste that is easy to apply. When the exhaust system of an internal combustion engine heats up to its operating temperature, the heat drives out all of the excess water from the paste. The silicate compounds that are left over have glass like properties, making a temporary, brittle repair.

Sodium silicate is also used currently as an exhaust system joint and crack sealer for repairing mufflers, resonators, tailpipes, and other exhaust components, with and without fiberglass reinforcing tapes. In this application, the sodium silicate (60–70%) is typically mixed with kaolin (40 30%), an aluminium silicate mineral, to make the sodium silicate "glued" joint opaque. The sodium silicate, however, is the high temperature adhesive; the kaolin serves simply as a compatible high temperature coloring agent. Some of these repair compounds also contain glass fibres to enhance their gap filling abilities and reduce brittleness. Sodium silicate can be used to fill gaps within the head gasket. Commonly used on aluminum alloy cylinder heads, which are sensitive to thermally induced surface deflection. This can be caused by many things including head bolt stretching, deficient coolant delivery, high cylinder head pressure, overheating, etc. "Liquid glass" (sodium silicate) is added to the system through the radiator, and allowed to circulate. Sodium silicate is suspended in the coolant until it reaches the cylinder head. At 100–105 °C (212 221 °F), sodium silicate loses water molecules to form a glass seal with a remelt temperature above 810 °C (1,490 °F). A sodium silicate repair can last two years or longer. The repair occurs rapidly, and symptoms disappear instantly. This repair works only when the sodium silicate reaches its "conversion" temperature at 100–105 °C. Contamination of engine oil is a serious possibility in situations in which a coolant to oil leak is present. Sodium silicate (glass particulate) contamination of lubricants is detrimental to their function. Sodium silicate solution is used to inexpensively, quickly, and permanently disable automobile engines. Running an engine with about 2 liters of a sodium silicate solution instead of motor oil causes the solution to precipitate, catastrophically damaging the engine's bearings and pistons within a few minutes. In the United States, this procedure was used to comply with requirements of the Car Allowance Rebate System (CARS) program.

A mixture of sodium silicate and sawdust has been used in between the double skin of certain safes. This not only makes them more fire resistant, but also makes cutting them open with an oxyacetylene torch extremely difficult due to the smoke emitted.

When crystals of a number of metallic salts are dropped into a solution of water glass, simple or branching stalagmites of coloured metal silicates are formed. This phenomenon has been used by manufacturers of toys and chemistry sets to provide instructive enjoyment to many generations of children from the early 20th century until the present. An early mention of crystals of metallic salts forming a "chemical garden" in sodium silicate is found in the 1946 Modern Mechanix magazine. Metal salts used included the sulfates and/or chlorides of copper, cobalt, iron, nickel, and manganese.

Sodium silicate is used as a deflocculant in casting slips helping reduce viscosity and the need for large amounts of water to liquidize the clay body. It is also used to create a crackle effect in pottery, usually wheel thrown. A vase or bottle is thrown on the wheel, fairly narrow and with thick walls. Sodium silicate is brushed on a section of the piece. After 5 minutes, the wall of the piece is stretched outward with a rib or hand. The result is a wrinkled or cracked look. It is also the main agent in "magic water", which is used when joining clay pieces, especially if the moisture level of the two differs.

Sodium silicate with additives was injected into the ground to harden it and thereby to prevent further leakage of highly radioactive water from the Fukushima Daiichi nuclear power plant in Japan in April, 2011. The residual heat carried by the water used for cooling the damaged reactors accelerated the setting of the injected mixture. On June 3, 1958, the USS Nautilus, the world's first nuclear submarine, visited Everett and Seattle. In Seattle, crewmen dressed in civilian clothing were sent in to secretly buy 140 quarts (160 liters) of an automotive product containing sodium silicate (originally identified as Stop Leak) to repair a leaking condenser system. The Nautilus was en route to the North Pole on a top secret mission to cross the North Pole submerged.

A historical use of the adhesive properties of sodium silicates is the production of paper cartridges for black powder revolvers produced by Colt's Manufacturing Company during the period from 1851 until 1873, especially during the American Civil War. Sodium silicate was used to seal combustible nitrated paper together to form a conical paper cartridge to hold the black powder, as well as to cement the lead ball or conical bullet into the open end of the paper cartridge. Such sodium silicate cemented paper cartridges were inserted into the cylinders of revolvers, thereby speeding the reloading of cap and ball black powder revolvers. This use largely ended with the introduction of Colt revolvers employing brass cased cartridges starting in 1873. Similarly, sodium silicate was also used to cement the top wad into brass shotgun shells, thereby eliminating any need for a crimp at the top of the brass shotgun shell to hold a shotgun shell together. Reloading brass shotgun shells was widely practiced by self reliant American farmers during the 1870s, using the same waterglass material that was also used to preserve eggs. The cementing of the top wad on a shotgun shell consisted of applying from three to five drops of waterglass on the top wad to secure it to the brass hull. Brass hulls for shotgun shells were superseded by paper hulls starting around 1877. The newer paper hulled shotgun shells used a roll crimp in place of a waterglass cemented joint to hold the top wad in the shell. However, whereas brass shotshells with top wads cemented with waterglass could be reloaded nearly indefinitely (given powder, wad, and shot, of course), the paper hulls that replaced the brass hulls could be reloaded only a few times.

Sodium silicate and other silicates are the primary components in "instant" wrinkle remover creams, which temporarily tighten the skin to minimize the appearance of wrinkles & under eye bags. These creams, when applied as a thin film and allowed to dry for a few minutes, can present dramatic results. This effect is not permanent, lasting from a few minutes up to a couple of hours. It works like water cement, once the muscle starts to move, it cracks and leaves white residues on the skin.

Waterglass has been used as an egg preservative with large success, primarily when refrigeration is not available. Fresh laid eggs are immersed in a solution of sodium silicate (waterglass). After being immersed in the solution they were removed and allowed to dry. A permanent air tight coating remains on the eggs. If they are then stored in appropriate environment, the majority of bacteria which would otherwise cause them to spoil are kept out and their moisture is kept in. According to the cited source, treated eggs can be kept fresh using this method for up to five months. When boiling eggs so preserved, the shell is no longer permeable to air, and the egg will tend to crack unless a hole in the shell is made (e. g. with a pin) in order to allow steam to escape.

Sodium silicate flocculant properties are also used to clarify wine and beer by precipitating colloidal particles. As a clearing agent, though, sodium silicate is sometimes confused with isinglass which is prepared from collagen extracted from the dried swim bladders of sturgeon and other fishes. Eggs preserved in a bucket of waterglass gel, and their shells are sometimes also used (baked and crushed) to clear wine.

Sodium silicate gel is also used as a substrate for algal growth in aquaculture hatcheries.