Вольфрамит: состав, свойства и месторождения

Iron manganese tungstate mineral

Wolframite is an iron, manganese, and tungstate mineral with a chemical formula of |(Fe,Mn)WO4 that is the intermediate mineral between ferberite (|Fe(2+) rich) and hübnerite (|Mn(2+) rich). Along with scheelite, the wolframite series are the most important tungsten ore minerals. Wolframite is found in quartz veins and pegmatites associated with granitic intrusives. Associated minerals include cassiterite, scheelite, bismuth, quartz, pyrite, galena, sphalerite, and arsenopyrite. This mineral was historically found in Europe in Bohemia, Saxony, and in the UK in Devon and Cornwall. China reportedly has the world's largest supply of tungsten ore with about 60%. Other producers are Spain, Canada, Portugal, Russia, Australia, Thailand, South Korea, Rwanda, Bolivia, the United States, and the Democratic Republic of the Congo.

The wolframite series is mainly formed through magmatic hydrothermal processes associated with felsic magmas, namely skarns, or through metamorphic processes. In the more common granitic deposits, wolframite minerals can be found in both greisen and veins as its formation is tied to these two structures.

The wolframite series consists of two endmembers, ferberite (Fe2+ end member), hübnerite (Mn2+ end member), with Wolframite, (Fe,Mn)WO4 itself being a solid solution between the two endmembers. Wolframite ore exhibits massive form with a dark grey to reddish black coloration.

The name "wolframite" is derived from German "wolf rahm", the name given to tungsten by Johan Gottschalk Wallerius in 1747. This, in turn, derives from "Lupi spuma", the name Georg Agricola used for the element in 1546, which translates into English as "wolf's froth" or "wolf's cream". The etymology is not entirely certain but seems to be a reference to the large amounts of tin consumed by the mineral during its extraction, the phenomenon being likened to a wolf eating a sheep. Wolfram is the basis for the chemical symbol W for tungsten as a chemical element.

As of 2022, estimated world mine production was 84,000 metric tons of tungsten. The foremost producer of Tungsten is China with an estimated 71,000 metric tons produced and as such world tungsten supply was dominated by China and Chinese exports. The next highest producers are Vietnam, Russia, Bolivia, and Rwanda with an estimated 4,800, 2,300, 1,400, and 1,100 respectively. Tungsten salts were used in the 19th century to dye cotton and to make stage costumes which were fire retardant. Additionally in the 19th century tungsten sulfides were sparingly used as lubrication for machining. Wolframite is also used to make tungstic acid which is used in the textile industry. A major modern day use of tungsten is as a catalyst for various chemical reactions. One such catalytic use of tungsten is as a hydrocracking catalyst which is used to improve the yield of organic components such as gasoline in hydrocarbon refinement as well as reducing harmful pollution and by products. Another catalytic use of tungsten is as a De NOX catalyst which is used in the treatment of nitrogen oxide emissions to convert harmful nitrogen oxides into inert N2 gas.