Үш электродты жүйеге арналған электрондық басқару жүйесі

Electronic system controlling a three electrode cell

A potentiostat is the electronic hardware required to control a three electrode cell and run most electroanalytical experiments. A Bipotentiostat and polypotentiostat are potentiostats capable of controlling two working electrodes and more than two working electrodes, respectively. The system functions by maintaining the potential of the working electrode at a constant level with respect to the reference electrode by adjusting the current at an auxiliary electrode. The heart of the different potentiostatic electronic circuits is an operational amplifier (op amp). It consists of an electric circuit which is usually described in terms of simple op amps.

This equipment is fundamental to modern electrochemical studies using three electrode systems for investigations of reaction mechanisms related to redox chemistry and other chemical phenomena. The dimensions of the resulting data depend on the experiment. In voltammetry, electric current in amps is plotted against electric potential in voltage. In a bulk electrolysis total coulombs passed (total electric charge) is plotted against time in seconds even though the experiment measures electric current (amperes) over time. This is done to show that the experiment is approaching an expected number of coulombs. Most early potentiostats could function independently, providing data output through a physical data trace. Modern potentiostats are designed to interface with a personal computer and operate through a dedicated software package. The automated software allows the user rapidly to shift between experiments and experimental conditions. The computer allows data to be stored and analyzed more effectively, rapidly, and accurately than the earlier standalone devices.

Replacing the CA, a control algorithm can maintain a constant voltage between the reference electrode and the working electrode. This algorithm is based on the rule of proportion:
(8)

is the last measured cell voltage between the working electrode (WE) and the counter electrode (CE). is the last measured electrochemical potential, i. e. the voltage between the reference electrode and WE to be kept constant. is the next cell voltage to be set, i. e. the controller output. is the setpoint, i. e. the desired
If the measurement intervals of Eq. (8) are kept constant, the control algorithm sets the cell voltage so to keep as close as possible to the setpoint The algorithm requires software controllable hardware such as a digital multimeter, a power supply, and a double pole double throw relay. The relay is necessary to switch polarity.

In electrochemical experiments the electrodes are the pieces of equipment that comes in immediate contact with the analyte. For this reason the electrodes are very important for determining the experimental result. The electrode surface may or may not catalyze chemical reactions. The size of the electrodes affects the magnitude of the currents passed which can affect signal to noise. But electrodes are not the only limiting factor for electrochemical experiments, the potentiostat also has a limited range of operation. The following are a few significant features that vary between instruments. Electric potential range (measured and applied): while the potential window is mostly based on the solvent window the electronics can also limit the possible range. Accuracy in potential (measured and applied): limits of deviations between the actual and reported. Range of scan rate: how slow or fast a potential window can be scanned. This is most important for experiments that require high scan rates such as those involving ultramicroelectrodes. Sample rate: the rate at which potential or voltage can be accurately sampled. This can be important for experiments that need high scan rates such as those involving ultramicroelectrodes. File size: a limiting factor can be the file size limit. This would most likely affect the choice of the potential range swept or the potential sample rate. Electric current range (measured and applied): the maximum range over which current can be sampled. Applying large currents is important for experiments that pass a great deal of current like a large bulk electrolysis. Measuring small currents is important for experiments that pass small currents like those involving ultramicroelectrodes. Current resolution: determines the operational range of a specific experiment and the bit resolution of that data in the current dimension. Accuracy in current (measured and applied): limits of deviations between the actual and reported. Number of working channels: how many working electrodes can the instrument control. A bipotentiostat is necessary to controlling systems with two working electrodes like a rotating ring disk electrode. A polypotentiostat may be important for controlling some biological experiments with three or more working electrodes. In conjunction with a Zero Resistance Ammeter per electrode many polarisations can be monitored at the same time in the same cell around the he couple potential. If the Zero Resistance Ammeters have an offsetting ability, then multiple tests can be achieved at the same time in the same test cell around the individual rest potential of each electrode. Such features can be useful for corrosion monitoring of coated electrodes or segmented but otherwise coupled welds. Footprint: potentiostats include small devices of about 20 x 10 x 5 cm weighing well under a kilogram or a simple board that can be installed in a desktop computer. A large bench top model would be on the order of 50 x 20 x 10 cm and weigh up to or more than 5 kilograms. Interface: can the instrument run independently or must it be slaved to a personal computer. Sweep generator: can the system apply an analogue sweep or does it use a digital staircase generator as an approximation. If it does use a digital staircase then the resolution of the staircase is important. Rotating electrode: can the instrument operate a rotating electrode. This is intrinsic for experiments that require a rotating disk electrode or rotating ring disk electrode.