Жарық поляризация жазықтығының бұрылуы хиральды материалдарда

Rotation of the plane of linearly polarized light as it travels through a chiral material

Optical rotation, also known as polarization rotation or circular birefringence, is the rotation of the orientation of the plane of polarization about the optical axis of linearly polarized light as it travels through certain materials. Circular birefringence and circular dichroism are the manifestations of optical activity. Optical activity occurs only in chiral materials, those lacking microscopic mirror symmetry. Unlike other sources of birefringence which alter a beam's state of polarization, optical activity can be observed in fluids. This can include gases or solutions of chiral molecules such as sugars, molecules with helical secondary structure such as some proteins, and also chiral liquid crystals. It can also be observed in chiral solids such as certain crystals with a rotation between adjacent crystal planes (such as quartz) or metamaterials. When looking at the source of light, the rotation of the plane of polarization may be either to the right (dextrorotatory or dextrorotary — d rotary, represented by (+), clockwise), or to the left (levorotatory or levorotary — l rotary, represented by (−), counter clockwise) depending on which stereoisomer is dominant. For instance, sucrose and camphor are d rotary whereas cholesterol is l rotary. For a given substance, the angle by which the polarization of light of a specified wavelength is rotated is proportional to the path length through the material and (for a solution) proportional to its concentration. Optical activity is measured using a polarized source and polarimeter. This is a tool particularly used in the sugar industry to measure the sugar concentration of syrup, and generally in chemistry to measure the concentration or enantiomeric ratio of chiral molecules in solution. Modulation of a liquid crystal's optical activity, viewed between two sheet polarizers, is the principle of operation of liquid crystal displays (used in most modern televisions and computer monitors).

Dextrorotation and laevorotation (also spelled levorotation) in chemistry and physics are the optical rotation of plane polarized light. From the point of view of the observer, dextrorotation refers to clockwise or right handed rotation, and laevorotation refers to counterclockwise or left handed rotation. A chemical compound that causes dextrorotation is dextrorotatory or dextrorotary, while a compound that causes laevorotation is laevorotatory or laevorotary. Compounds with these properties consist of chiral molecules and are said to have optical activity. If a chiral molecule is dextrorotary, its enantiomer (geometric mirror image) will be laevorotary, and vice versa. Enantiomers rotate plane polarized light the same number of degrees, but in opposite directions.

A compound may be labeled as dextrorotary by using the "(+) " or "d " prefix. Likewise, a laevorotary compound may be labeled using the "(−) " or "l " prefix. The lowercase "d " and "l " prefixes are obsolete, and are distinct from the SMALL CAPS "D " and "L " prefixes. The "D " and "L " prefixes are used to specify the enantiomer of chiral organic compounds in biochemistry and are based on the compound's absolute configuration relative to (+) glyceraldehyde, which is the D form by definition. The prefix used to indicate absolute configuration is not directly related to the (+) or (−) prefix used to indicate optical rotation in the same molecule. For example, nine of the nineteen L amino acids naturally occurring in proteins are, despite the L prefix, actually dextrorotary (at a wavelength of 589 nm), and D fructose is sometimes called "laevulose" because it is laevorotary. The D and L prefixes describe the molecule as a whole, as do the (+) and (−) prefixes for optical rotation. In contrast, the (R) and (S) prefixes from the Cahn–Ingold–Prelog priority rules characterize the absolute configuration of each specific chiral stereocenter with the molecule, rather than a property of the molecule as a whole. A molecule having exactly one chiral stereocenter (usually an asymmetric carbon atom) can be labeled (R) or (S), but a molecule having multiple stereocenters needs more than one label. For example, the essential amino acid L threonine contains two chiral stereocenters and is written (2S,3S) threonine. There is no strict relationship between the R/S, the D/L, and (+)/(−) designations, although some correlations exist. For example, of the naturally occurring amino acids, all are L, and most are (S). For some molecules the (R) enantiomer is the dextrorotary (+) enantiomer, and in other cases it is the laevorotary (−) enantiomer. The relationship must be determined on a case by case basis with experimental measurements or detailed computer modeling.

The rotation of the orientation of linearly polarized light was first observed in 1811 in quartz by French physicist François Arago. In 1820, the English astronomer Sir John F. W. Herschel discovered that different individual quartz crystals, whose crystalline structures are mirror images of each other (see illustration), rotate linear polarization by equal amounts but in opposite directions. Jean Baptiste Biot also observed the rotation of the axis of polarization in certain liquids and vapors of organic substances such as turpentine. In 1822, Augustin Jean Fresnel found that optical rotation could be explained as a species of birefringence: whereas previously known cases of birefringence were due to the different speeds of light polarized in two perpendicular planes, optical rotation was due to the different speeds of right hand and left hand circularly polarized light. Simple polarimeters have been used since this time to measure the concentrations of simple sugars, such as glucose, in solution. In fact one name for D glucose (the biological isomer), is dextrose, referring to the fact that it causes linearly polarized light to rotate to the right or dexter side. In a similar manner, levulose, more commonly known as fructose, causes the plane of polarization to rotate to the left. Fructose is even more strongly levorotatory than glucose is dextrorotatory. Invert sugar syrup, commercially formed by the hydrolysis of sucrose syrup to a mixture of the component simple sugars, fructose, and glucose, gets its name from the fact that the conversion causes the direction of rotation to "invert" from right to left. In 1849, Louis Pasteur resolved a problem concerning the nature of tartaric acid. A solution of this compound derived from living things (to be specific, wine lees) rotates the plane of polarization of light passing through it, but tartaric acid derived by chemical synthesis has no such effect, even though its reactions are identical and its elemental composition is the same. Pasteur noticed that the crystals come in two asymmetric forms that are mirror images of one another. Sorting the crystals by hand gave two forms of the compound: Solutions of one form rotate polarized light clockwise, while the other form rotate light counterclockwise. An equal mix of the two has no polarizing effect on light. Pasteur deduced that the molecule in question is asymmetric and could exist in two different forms that resemble one another as would left and right hand gloves, and that the organic form of the compound consists of purely the one type. In 1874, Jacobus Henricus van 't Hoff and Joseph Achille Le Bel independently proposed that this phenomenon of optical activity in carbon compounds could be explained by assuming that the 4 saturated chemical bonds between carbon atoms and their neighbors are directed towards the corners of a regular tetrahedron. If the 4 neighbors are all different, then there are two possible orderings of the neighbors around the tetrahedron, which will be mirror images of each other. This led to a better understanding of the three dimensional nature of molecules. In 1945, Charles William Bunn predicted optical activity of achiral structures, if the wave's propagation direction and the achiral structure form an experimental arrangement that is different from its mirror image. Such optical activity due to extrinsic chirality was observed in the 1960s in liquid crystals. In 1950, Sergey Vavilov predicted optical activity that depends on the intensity of light and the effect of nonlinear optical activity was observed in 1979 in lithium iodate crystals. Optical activity is normally observed for transmitted light. However, in 1988, M. P. Silverman discovered that polarization rotation can also occur for light reflected from chiral substances. Shortly after, it was observed that chiral media can also reflect left handed and right handed circularly polarized waves with different efficiencies. These phenomena of specular circular birefringence and specular circular dichroism are jointly known as specular optical activity. Specular optical activity is very weak in natural materials. In 1898 Jagadish Chandra Bose described the ability of twisted artificial structures to rotate the polarization of microwaves. Since the early 21st century, the development of artificial materials has led to the prediction and realization of chiral metamaterials with optical activity exceeding that of natural media by orders of magnitude in the optical part of the spectrum. Extrinsic chirality associated with oblique illumination of metasurfaces lacking two fold rotational symmetry has been observed to lead to large linear optical activity in transmission and reflection, as well as nonlinear optical activity exceeding that of lithium iodate by 30 million times.

For a pure substance in solution, if the color and path length are fixed and the specific rotation is known, the observed rotation can be used to calculate the concentration. This usage makes a polarimeter a tool of great importance to those trading in or using sugar syrups in bulk.

Rotation of light's plane of polarization may also occur through the Faraday effect which involves a static magnetic field. However, this is a distinct phenomenon that is not classified as "optical activity." Optical activity is reciprocal, i. e. it is the same for opposite directions of wave propagation through an optically active medium, for example clockwise polarization rotation from the point of view of an observer. In case of optically active isotropic media, the rotation is the same for any direction of wave propagation. In contrast, the Faraday effect is non reciprocal, i. e opposite directions of wave propagation through a Faraday medium will result in clockwise and anti clockwise polarization rotation from the point of view of an observer. Faraday rotation depends on the propagation direction relative to that of the applied magnetic field. All compounds can exhibit polarization rotation in the presence of an applied magnetic field, provided that (a component of) the magnetic field is oriented in the direction of light propagation. The Faraday effect is one of the first discoveries of the relationship between light and electromagnetic effects.