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1966 song by Marvin Gaye and Tammi Terrell

"Ain't No Mountain High Enough" is a song written by Nickolas Ashford & Valerie Simpson in 1966 for the Tamla label, a division of Motown. The composition was first successful as a 1967 hit single recorded by Marvin Gaye and Tammi Terrell, and became a hit again in 1970 when recorded by former Supremes frontwoman Diana Ross. The song became Ross's first solo number one hit on the Billboard Hot 100 chart and was nominated for the Grammy Award for Best Female Pop Vocal Performance.

The song was written by Ashford and Simpson prior to joining Motown. British soul singer Dusty Springfield wanted to record the song but the duo declined, hoping it would give them access to the Detroit based label. As Valerie Simpson later recalled, "We played that song for her (Springfield) but wouldn't give it to her, because we wanted to hold that back. We felt like that could be our entry to Motown. Nick called it the 'golden egg'." Springfield recorded a similar verse melody in "I'm Gonna Leave You" on Dusty. The original 1967 version of "Ain't No Mountain High Enough" was a top 20 hit. According to record producers, Terrell was a little nervous and intimidated during the recording sessions because she did not rehearse the lyrics. Terrell recorded her vocals alone with producers Harvey Fuqua and Johnny Bristol, who added Gaye's vocal at a later date. "Ain't No Mountain" peaked at number 19 on the Billboard pop charts, and went to number three on the R&B charts. Billboards original review of the single stated: "Chalk up another pulsating fast smash for Gaye with his new partner Tammi Terrell. The electricity of the duo combined with the blockbuster rhythm material grooves all the way." This original version of "Ain't No Mountain", produced by Fuqua and Bristol, was a care free, danceable, and romantic love song that became the signature duet between Gaye and Terrell. Its success led to a string of more Ashford/Simpson penned duets (including "You're All I Need to Get By", "Ain't Nothing Like the Real Thing", and "Your Precious Love"). In 1999, the Gaye/Terrell version was inducted into the Grammy Hall of Fame. The Gaye/Terrell version was included in the soundtrack for the 1998 film Stepmom, the 2000 film Remember the Titans as well as the 2014 film Guardians of the Galaxy.

Diana Ross & the Supremes recorded a version of "Ain't No Mountain High Enough", which was more faithful to the Terrell Gaye original version, as a duet with The Temptations. That song was an album cut from a joint LP released by Motown Records in 1968 on the two superstar groups, titled Diana Ross & the Supremes Join the Temptations.