Дихлорметан: свойства, применение и риски для здоровья.

Dichloromethane (DCM, methylene chloride, or methylene bichloride) is an organochlorine compound with the formula |CH2Cl2. This colorless, volatile liquid with a chloroform like, sweet odor is widely used as a solvent. Although it is not miscible with water, it is slightly polar, and miscible with many organic solvents.

Natural sources of dichloromethane include oceanic sources, macroalgae, wetlands, and volcanoes. However, the majority of dichloromethane in the environment is the result of industrial emissions.

DCM's volatility and ability to dissolve a wide range of organic compounds makes it a useful solvent for many chemical processes. Its volatility has led to its use as an aerosol spray propellant and as a blowing agent for polyurethane foams.

The chemical compound's low boiling point allows the chemical to function in a heat engine that can extract mechanical energy from small temperature differences. An example of a DCM heat engine is the drinking bird. The toy works at room temperature. It is also used as the fluid in jukebox displays and holiday bubble lights that have a colored bubbling tube above a lamp as a source of heat and a small amount of rock salt to provide thermal mass and a nucleation site for the phase changing solvent. DCM chemically welds certain plastics. For example, it is used to seal the casing of electric meters. Often sold as a main component of plastic welding adhesives, it is also used extensively by model building hobbyists for joining plastic components together. It is commonly referred to as "Di clo". It is used in the garment printing industry for removal of heat sealed garment transfers. DCM is used in the material testing field of civil engineering; specifically it is used during the testing of bituminous materials as a solvent to separate the binder from the aggregate of an asphalt or macadam to allow the testing of the materials. Dichloromethane extract of Asparagopsis taxiformis, a seaweed fodder for cattle, has been found to reduce their methane emissions by 79%. It has been used as the principal component of various paint and lacquer strippers, although its use is now restricted in the EU and many such products now use benzyl alcohol as a safer alternative.

Serious health risks are associated with DCM, despite being one of the least toxic simple chlorohydrocarbons. Its high volatility makes it a inhalation hazard. It can also be absorbed through the skin. Symptoms of acute overexposure to dichloromethane via inhalation include difficulty concentrating, dizziness, fatigue, nausea, headaches, numbness, weakness, and irritation of the upper respiratory tract and eyes. More severe consequences can include suffocation, loss of consciousness, coma, and death. Acute exposure by inhalation has resulted in optic neuropathy and hepatitis. Prolonged skin contact can result in DCM dissolving some of the fatty tissues in skin, resulting in skin irritation or chemical burns. It may be carcinogenic, as it has been linked to cancer of the lungs, liver, and pancreas in laboratory animals. Other animal studies showed breast cancer and salivary gland cancer. Research is not yet clear as to what levels may be carcinogenic to humans. In animal experiments, it was fetotoxic at doses that were maternally toxic but no teratogenic effects were seen. In the European Union, the Scientific Committee on Occupational Exposure Limit Values (SCOEL) recommends an occupational exposure limit for DCM of 100 ppm (8 hour time weighted average) and a short term exposure limit of 200 ppm for a 15 minute period. The European Parliament voted in 2009 to ban the use of DCM in paint strippers for consumers and many professionals, with the ban taking effect in December 2010. In February 2013, the US Occupational Safety and Health Administration (OSHA) and the National Institute for Occupational Safety and Health warned that at least 14 bathtub refinishers have died since 2000 from DCM exposure. These workers had been working alone, in poorly ventilated bathrooms, with inadequate or no respiratory protection, and no training about the hazards of DCM. OSHA has since then issued a DCM standard. On March 15, 2019, the US Environmental Protection Agency (EPA) issued a final rule to prohibit the manufacture (including importing and exporting), processing, and distribution of DCM in all paint removers for consumer use, effective in 180 days. However, it does not affect other products containing DCM, including many consumer products not intended for paint removal. On April 20, 2023, the EPA proposed a widespread ban on the production of DCM with some exceptions for military and industrial uses.

Dichloromethane is not classified as an ozone depleting substance by the Montreal Protocol. The US Clean Air Act does not regulate dichloromethane as an ozone depleter. Dichloromethane has been classified as a very short lived substance (VSLS). Despite their short atmospheric lifetimes of less than 0.5 year, can contribute to stratospheric ozone depletion, particularly if emitted in regions where rapid transport to the stratosphere occurs. Atmospheric abundances of dichloromethane have been increasing in recent years.