Янтарь китов: Происхождение, свойства и ценность

Substance produced in the digestive system of sperm whales

Ambergris ('/æ//m//b//ər//g//r//iː//s/// or '/æ//m//b//ər//g//r//ɪ//s///; ambra grisea; ), ambergrease, or grey amber is a solid, waxy, flammable substance of a dull grey or blackish colour produced in the digestive system of sperm whales. Freshly produced ambergris has a marine, fecal odor. It acquires a sweet, earthy scent as it ages, commonly likened to the fragrance of isopropyl alcohol without the vaporous chemical astringency. Ambergris has been highly valued by perfume makers as a fixative that allows the scent to last much longer, although it has been mostly replaced by synthetic ambroxide. Dogs are attracted to the smell of ambergris and are sometimes used by ambergris searchers.

The English word amber derives from the Arabic word ʿanbar (عنبر; ultimately from Middle Persian ambar, also ambergris), via Middle Latin ambar and Middle French ambre. The word "amber", in its sense of "ambergris", was adopted in Middle English in the 14th century. The addition of "grey" came about when, in the Romance languages, the sense of the word "amber" was extended to Baltic amber (fossil resin), as white or yellow amber (ambre jaune), from as early as the late 13th century.

Ambergris is formed from a secretion of the bile duct in the intestines of the sperm whale, and can be found floating on the sea or washed up on coastlines. It is sometimes found in the abdomens of dead sperm whales. Another theory states that an ambergris mass is formed when the colon of a whale is enlarged by a blockage from intestinal worms and cephalopod parts resulting in the death of the whale and the mass being excreted into the sea. Ambergris takes years to form. Christopher Kemp, the author of Floating Gold: A Natural (and Unnatural) History of Ambergris, says that it is only produced by sperm whales, and only by an estimated one percent of them. Ambergris is rare; once expelled by a whale, it often floats for years before making landfall. The slim chances of finding ambergris and the legal ambiguity involved led perfume makers away from ambergris, and led chemists on a quest to find viable alternatives. Ambergris is found primarily in the Atlantic Ocean and on the coasts of South Africa; Brazil; Madagascar; the East Indies; The Maldives; China; Japan; India; Australia; New Zealand; and the Molucca Islands. Most commercially collected ambergris comes from the Bahamas in the Atlantic, particularly New Providence. In 2021, fishermen found a 127 kg (280 pound) piece of ambergris off the coast of Yemen, valued at US$1.5 million. Fossilised ambergris from 1.75 million years ago has also been found.

Ambergris is found in lumps of various shapes and sizes, usually weighing from to or more. can be separated from ambergris by heating raw ambergris in alcohol, then allowing the resulting solution to cool. Breakdown of the relatively scentless ambrein through oxidation produces ambroxide and ambrinol, the main odor components of ambergris. Ambroxide is now produced synthetically and used extensively in the perfume industry.